Asked around and got a ride from a very nice local going to Udina. He took us to the other station near Udine (Palmanova) at the highway intersecting direction Slovenia-Austria. He went and asked other italian people for 5 mins to pick us up next. Very funny guy. The gas station is filled with locals so you have to asked around and be ready to wait a bit.
For direction Brno and east/south europe, probably best there is. One turkish guy offered ride to Istanbul but we were two so couldnt fit with bags. At Mcdonalds parking we asked a older man and he drove us all the way to gas station near Brno.